Product Details:
Product Name：tert-Butyldiphenylphosphine
CAS:6002-34-2
Synonyms：
NSC 244302;
Tert-Butyldiphenylphosphine ;
(1,1-Dimethylethyl)diphenylphosphine;
Diphenyl(tert-butyl)phosphine;
TERT-BUTYLDIPHENYLPHOSPHINE;
Phosphine,(1,1-dimethylethyl)diphenyl-;
Tert-butyl(diphenyl)phosphane
MF： C16H19P
MW： 242.3
CAS： 6002-34-2
Melting point : 52-55 °C(lit.)
Boiling point: 144-146 °C2 mm Hg(lit.)
Storage temp. : Inert atmosphere,Room Temperature
Uses1:
New family of Ph2(t-Bu)P phosphines for efficient Silyl-Heck transformations.
Uses2:
Catalyst for:
●Nickel/Lewis acid-catalyzed carbocyanation of alkynes with acetonitrile or substituted acetonitriles
●Palladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditions
●Palladium to form a catalyst for methoxycarbonylation reactions
●Ru-catalyzed transfer hydrogenation in reductive coupling of disubstituted allenes with aldehydes
●Stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes
●Phosphine ligand in nickel-catalyzed carbocyanation of alkynes
●Monodentate P-Donor Ligands (LKB-P)
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