Product Details:
Product Name：Tricyclohexylphosphonium tetrafluoroborate
CAS:58656-04-5
Synonyms：
TricyclohexylphosphinetetrafluroboratePcy3HBF4;
TricyclohexylphosphinetetrafluoroborateINStockCOATDSfreesample;
TricyclohexylphosphinetetrafluoroborateINStockMSDS;
TricyclohexylphosphinetChemicalbooketrafluoroborateINStockfreesampleand;
Phosphine,tricyclohexyl-,tetrafluoroborate(1-)(1:1);
TRICYCLOHEXYLPHOSPHONIUMTETRA;
TricyclohexylphosphoniuMtetrafluoroborate,Cy3PH+BF4-;
MF： C18H34BF4P
MW： 368.24
CAS： 58656-04-5
Melting point: 164 °C(lit.)
storage temp. : Keep in dark place,Sealed in dry,Room Temperature
Form: Powder
Water Solubility: Soluble in water.
Reactions:
Non-pyrophoric, air-stable derivative suitable as a replacement for the neat phosphine in a variety of stoichiometric and catalytic processes.
Uses1:
Tricyclohexylphosphonium Tetrafluoroborate acts as a reagent in the synthesis of potent JAK2 inhibitor BMS-911543 as a potential treatment for myeloproliferative disorders, preparation of Lapatinib intermediate via arylation of furfural with bromochlorofluorobenzyloxyphenylquinazolinamine, structure-activity relationships of carboline and carbazole derivatives as ATP-competitive kinesin spindle protein inhibitors.
Uses2:
Tricyclohexylphosphine tetrafluoroborate may be used in the following processes:
1.As a ligand for preparing C-homoaporphine alkaloids via microwave-assisted direct-arylation.
2.To synthesize poly-[9,9-bis(3-propylamide-2-methylpropyl sulfonic acid) fluorene]-co-(4,4′-diphenyl) (PFDBSO3H), which can be employed as a template and doping agent for enhancing the conductivity of poly(3,4-ethylenedioxythiophene) (PEDOT) films.
3.To improve the reactivity of palladium-catalyzed Suzuki-Miyaura cross-coupling reaction between MIDA boronates and less activated alkenyl tosylates.
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