Product Details:
Product Name:Tri-tert-butylphosphine
CAS:13716-12-6
Synonyms:
Tri-tert-butylphosphine
Tri-t-butylphosphosphin;
TRI-TERT-BUTYLPHOSPHINE;
tris(1,1-dimethylethyl)phosphine
MF: C12H27P
MW: 202.32
CAS: 13716-12-6
Purity:98%
Melting point: 30-35 °C(lit.)
Boiling point: 102-103 °C13 mm Hg(lit.)
Density:0.861 g/mL at 25 °C
storage temp: Flammables area
Water Solubility :insoluble
Sensitive: Air & Moisture Sensitive
Hydrolytic Sensitivity 9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
Reaction: Useful as a ligand in a variety of palladium-catalyzed C-N, C-O and C-C bond-forming reactions under mild conditions.
Uses: Tri-tert-butylphosphine is used primarily in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.
Uses: Valuable ligand for several coupling reactions. This product is offered as the THF solution for more convenient handling.
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