Bis(cyclopentadienyl)zirconium Chloride Hydride CAS: 37342-97-5

Product Details:

Product Name：Bis(cyclopentadienyl)zirconium chloride hydride

CAS:37342-97-5

Synonyms：

ZIRCONOCENE CHLORIDE HYDRIDE;

Di(cyclopentadienyl)zirconium(IV) chloride hydride;

bis(3-cyclopentadienyl)chlorohydrurozirconium;Bis(cyclopentadienyl)zirconium chloride hydride (Schwartz's Reagent);

Bis(cyclopentadienyl)zirconiumchloridehydride~Schwartz'sReagent~Zirconocenehydrochloride;

Zirconocenechloridehydride;

Bis(cyclopentadienyl)zirconiumchloridehydride(Schwartz'sReagent);

Di(cyclopentadienyl)zirconium(IV) chloride hydride, Schwartz reagent, Zirconocene chloride hydride

CAS: 37342-97-5

MF: C10H11ClZr

MW: 257.87

Melting point: 300 °C

Storage temp: Keep in dark place,Inert atmosphere,2-8°C

Form: Powder

Water Solubility: reacts

Sensitive: Light, Air & Moisture Sensitive

Reaction:

1.Reagent for the hydrozirconation of olefins.

2.Reagent for the hydrozirconation of alkynes.

3.Catalyst for the hydroboration of olefins.

4.Mediates the reduction of tertiary amides to aldehydes, without reduction of cyano, nitro, ester, or α,β-unsaturated groups.

5.Catalyst for the asymmetric vinylation and dienylation of ketones.

6.Useful reagent for dimethylzinc mediated additions alkenylzirconocenes to aldimines.

7.Useful reagent for the synthesis of oxidized amides from nitriles.

8.Reagent for the hydrozirconation of propargylic alcohols.

Uses1:

Functionalization of unsaturated systems via an organozirconium intermediate.

Uses2:

Bis(cyclopentadienyl)zirconium hydridochloride is used in the conversion of amides to aldehydes. It is also used as a pharmaceutical intermediate.

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